| Christian Clavier | Napoléon Bonaparte [HR] | |
| Gérard Depardieu | Joseph Fouché [HR] | |
| Isabella Rossellini | Joséphine de Beauharnais [HR] | |
| John Malkovich | Talleyrand [HR] | |
| Anouk Aimée | Letitia Bonaparte [NR] | |
| Heino Ferch | Armand Augustin Louis, Marquis de Caulaincourt [NR] | |
| Sebastian Koch | Jean Lannes [NR] | |
| Ennio Fantastichini | Joseph Bonaparte [NR] | |
| Guillaume Depardieu | Muiron [NR] | |
| Julian Sands | Klemens von Metternich [NR] | |
| Toby Stephens | Kaiser Alexander I. [NR] | |
| John Wood | Papst Pius VII. [NR] | |
| Marie Bäumer | Caroline Bonaparte [NR] | |
| Claudio Amendola | Murat [NR] | |
| Mavie Hörbiger | Marie-Louise von Österreich [NR] | |
| Natacha Amal | Madame Bertrand [NR] | |
| Fabienne Babe | Madame de Staël [NR] | |
| André Chaumeau | Ludwig XVIII. [NR] | |
| Constance Dollé | Pauline [NR] | |
| Alain Doutey | Maréchal Ney [NR] | |
| Serge Dupire | Cambronne [NR] | |
| Tamsin Egerton | Betzy [NR] | |
| Vincent Grass | Karl IV. von Spanien [NR] | |
| Christopher Heyerdahl | Geoffroy St-Hilaire [NR] | |
| Yves Jacques | Lucien Bonaparte [NR] | |
| Alexandra Maria Lara | Marie Walewska [NR] | |
| Jacky Nercessian | Roustam [NR] | |
| Florence Pernel | Madame Tallien [NR] | |
| Ludivine Sagnier | Hortense de Beauharnais [NR] | |
| Charlotte Valandrey | Madame Coigny [NR] | |
| Philippe Volter | Barras [NR] | |
